Monday, August 20, 2012

Reactive Glass


The latest 'hot new' thing in warm glass seems to be 'reactive glass'. I say 'new' though it has always been there in some respects because of the chemical composition of different coloured glass and the chemical reactions between them and metal (Silver, Gold and Copper) inclusions. Bullseye started producing special reactive glass about five years ago and Spectrum joined in a few years ago.

It is a simple development really. Glass (simplistically) is made up of sand (Silica) and potash (Potassium) or soda (Calcium Carbonate) plus metals (Copper, Lead, Iron, Sulphur, Boron) for colour. The addition of Iron Oxide gives clear soda lime glass a greenish tint, Iron and Chromium (and indeed Uranium) create green glass, Sulphur gives amber, yellows and vanilla, Copper creates blue, Lead oranges and reds and so on. the elements in the glass will also react with silver, gold and copper metal inclusions like leaf, wire and grid.

So if a Copper bearing Blue/Green frit is scattered on Sulphur bearing vanilla glass the result is a dark amber glass. If Silver (Ag) leaf is placed on the vanilla it reacts and 'fumes' beyond the leaf itself to create red. If the Copper frit covers the silver then the silver leaf 'remains' blue. All three reactions can be seen above and two of the three below.

The glass manufacturers also produce reactive glass that is either white or clear. They react with Copper or Silver to produce a reddish hue. Not all glass will react and there is a lot of experimentation to develop the correct colour intensity. Spectrum and Bullseye both have useful fact sheets on their websites to give the glass artist some degree of predictability. The best part is that you get to play around a lot and particularly with powders and frits.

I have seen an artist's 'colour card' which shows the results of combining frit colours - over 600 combinations - and it is a fantastic tool. One day I will have to get around to doing it for a permanent reference chart.


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